With the men’s Olympic Golf competition completed, groupings for the first and second rounds of the women's Olympic Golf competition have been announced. Mone Inami (JPN), winner of five JLPGA events in 2021, will have the honor of hitting the opening tee shot to get the competition underway Wednesday at Kasumigaseki Country Club.
2016 Olympic Gold Medalist Inbee Park (KOR) will tee off at 8:41 a.m. alongside 2016 Silver Medalist Lydia Ko (NZL) and 2016 Bronze Medalist Shanshan Feng (CHN).
Nelly Korda (USA), who currently holds the top spot in the women’s world rankings, will start her first round at 8:14 a.m. alongside Jin Young Ko (KOR) and Nasa Hataoka (JPN).
Later in the morning, major champions Minjee Lee (AUS), Patty Tavatanakit (THA), and Sophia Popov (GER) will tee off at 10:14 a.m.
| R1 - Tee 1 | R2 - Tee 2 | Player 1 | Country | Player 2 | Country | Player 3 | Country |
| 7:30 | 9:25 | Mone Inami | JPN | Maria Fassi | MEX | Albane Valenzuela | SUI |
| 7:41 | 9:36 | Kelly Tan | MAS | Alena Sharp | CAN | Anne van Dam | NED |
| 7:52 | 9:47 | Leona Maguire | IRL | Bianca Pagdanganan | PHI | Matilda Castren | FIN |
| 8:03 | 10:03 | Mel Reid | GBR | Caroline Masson | GER | Anna Nordqvist | SWE |
| 8:14 | 10:14 | Nasa Hataoka | JPN | Jin Young Ko | KOR | Nelly Korda | USA |
| 8:25 | 10:25 | Brooke Henderson | CAN | Lexi Thompson | USA | Yuka Saso | PHI |
| 8:41 | 10:36 | Inbee Park | KOR | Lydia Ko | NZL | Shanshan Feng | CHN |
| 8:52 | 10:47 | Sanna Nuutinen | FIN | Maria Torres | PUR | Tiffany Chan | HKG |
| 9:03 | 10:58 | Klara Spilkova | CZE | Manon de Roey | BEL | Christine Wolf | AUT |
| 9:14 | 11:09 | Maha Haddioui | MAR | Lucrezia Colombotto Rosso | ITA | Daniela Darquea | ECU |
| 9:25 | 7:30 | Nanna Koerstz Madsen | DEN | Aditi Ashok | IND | Giulia Molinaro | ITA |
| 9:36 | 7:41 | Wei-Ling Hsu | TPE | Azahara Munoz | ESP | Jodi Ewart Shadoff | GBR |
| 9:47 | 7:52 | Xiyu Lin | CHN | EK Pedersen | DEN | Madelene Sagstrom | SWE |
| 10:03 | 8:03 | Jessica Korda | USA | Celine Boutier | FRA | Gaby Lopez | MEX |
| 10:14 | 8:14 | Minjee Lee | AUS | Patty Tavatanakit | THA | Sophia Popov | GER |
| 10:25 | 8:25 | Ariya Jutanugarn | THA | Hyojoo Kim | KOR | Carlota Ciganda | ESP |
| 10:36 | 8:41 | Danielle Kang | USA | Hannah Green | AUS | Sei Young Kim | KOR |
| 10:47 | 8:52 | Min Lee | TPE | Stephanie Meadow | IRL | Perrine Delacour | FRA |
| 10:58 | 9:03 | Mariajo Uribe | COL | Pia Babnik | SLO | Magdalena Simmermacher | ARG |
| 11:09 | 9:14 | Diksha Dagar | IND | Kim Metraux | SUI | Tonje Daffinrud | NOR |